ELECTROCHEMICAL ACTIVATION OF SULFUR-SYNTHESIS OF ORGANIC MONO AND TRISULFIDES WITH A SACRIFICIAL CARBON-SULFUR ANODE

Authors
LEGUILLANTON G DO QT ELOTHMANI D SIMONET J
Citation
G. Leguillanton et al., ELECTROCHEMICAL ACTIVATION OF SULFUR-SYNTHESIS OF ORGANIC MONO AND TRISULFIDES WITH A SACRIFICIAL CARBON-SULFUR ANODE, Phosphorus, sulfur and silicon and the related elements, 74(1-4), 1993, pp. 375-376
Citations number
3
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
74
Issue
1-4
Year of publication
1993
Pages
375 - 376
Database
ISI
SICI code
1042-6507(1993)74:1-4<375:EAOSOO>2.0.ZU;2-K
Abstract
The electrooxidation of sulfur in organic solvents leads to die format ion of the cationic species S2+. Macroscale electrolyses are carried o ut with a sacrificial carbon-sulfur anode. S2+ can react either with a romatics to give monosulfides by electrophilic substitution, or with n ucleophiles, thiols for example, to give trisulfides.