1,1-BIS(METHYLTHIO)-2-NITROETHENE, A VERSATILE SYNTHON FOR THE SYNTHESIS OF OXIMINOORTHOTHIOESTERS

Authors
COUSTARD JM JACQUESY JC
Citation
Jm. Coustard et Jc. Jacquesy, 1,1-BIS(METHYLTHIO)-2-NITROETHENE, A VERSATILE SYNTHON FOR THE SYNTHESIS OF OXIMINOORTHOTHIOESTERS, Phosphorus, sulfur and silicon and the related elements, 74(1-4), 1993, pp. 427-428
Citations number
6
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
74
Issue
1-4
Year of publication
1993
Pages
427 - 428
Database
ISI
SICI code
1042-6507(1993)74:1-4<427:1AVSFT>2.0.ZU;2-W
Abstract
1,1-bis(methylthio)-2-nitroethene gives a stable hydroxynitrilium ion in trifluoromethanesulfonic acid. This cation can be trapped by variou s nucleophiles to yield alpha-oximinoorthothioesters.