SYNTHESIS AND REACTIVITY OF TRANSITION ME TAL-SUBSTITUTED PHOSPHANES,ARSANES AND STIBANES .57. OXIDATION OF TERTIARY AND SECONDARY METALLOPHOSPHANES OF IRON AND TUNGSTEN WITH DIMETHYLDIOXIRANE

Authors
MALISCH W HINDAHL K GRUN K ADAM W PRECHTL F SHELDRICK WS
Citation
W. Malisch et al., SYNTHESIS AND REACTIVITY OF TRANSITION ME TAL-SUBSTITUTED PHOSPHANES,ARSANES AND STIBANES .57. OXIDATION OF TERTIARY AND SECONDARY METALLOPHOSPHANES OF IRON AND TUNGSTEN WITH DIMETHYLDIOXIRANE, Journal of organometallic chemistry, 509(2), 1996, pp. 209-214
Citations number
41
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of organometallic chemistry → ACNP
ISSN journal
0022328X
Volume
509
Issue
2
Year of publication
1996
Pages
209 - 214
Database
ISI
SICI code
0022-328X(1996)509:2<209:SAROTM>2.0.ZU;2-Q
Abstract
The reaction of the metallo-phosphines Cp(OC)(2)(L)W-PR(2) (L = CO, PR (2) = P((t)Bu)(2) (2a), P(o-Tol)(2) (2b), P(H)Mes (2c), P(Me)Mes (2d); L = Me(3)P, PR(2) = PPh(2) (2e)) and Cp(OC)(2)Fe-PR(2) (PR(2) = P((t) Bu)(2) (4a), P((t)Bu)(Pr-i) (4b)) with dimethyldioxirane leads to the corresponding metallo-phosphineoxides Cp(OC)(2)(L)W-P(O)R(2) (3a-3e) a nd Cp(OC)(2)Fe-P(O)R(2) (5a, 5b). The structure of Cp(OC)(3)W-P(O)(o-T ol)(2) (3b) is determined by X-ray analysis.