NEW BONDING MODE OF (DITHIOFORMATO)PHOSPHINE LIGAND - SYNTHESIS, REACTIVITY AND CRYSTAL-STRUCTURE OF [W(CO)5(PPH2CS2)]ET4N

Authors
YIH KH LIN YC CHENG MC WANG Y
Citation
Kh. Yih et al., NEW BONDING MODE OF (DITHIOFORMATO)PHOSPHINE LIGAND - SYNTHESIS, REACTIVITY AND CRYSTAL-STRUCTURE OF [W(CO)5(PPH2CS2)]ET4N, Journal of the Chemical Society, Chemical Communications, (18), 1993, pp. 1380-1382
Citations number
12
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
18
Year of publication
1993
Pages
1380 - 1382
Database
ISI
SICI code
0022-4936(1993):18<1380:NBMO(L>2.0.ZU;2-2
Abstract
The phosphorus coordination of the diphenyl(dithioformato)phosphine li gand in [W(CO)5(PPh2CS2)]Et4N, 1 has been confirmed by an X-ray diffra ction analysis; alkylation of 1 at the S atom results in the formation of W(CO)5[PPh2(CS2R)], 4 in high yield.