PI-FACE DIFFERENTIATION IN MICHAEL REACTION TO THE ENONE GROUP ADJACENT TO THE (ETA-C5H5)MO(CO)2(PI-ALLYL) FRAGMENT - A NEW APPROACH TO THESTEREOSELECTIVE SYNTHESIS OF 2,3,4,5-TETRASUBSTITUTED-TETRAHYDROFURANCOMPOUNDS

Authors
LIN SH CHENG WJ LIAO YL WANG SL LEE GH PENG SM LIU RS
Citation
Sh. Lin et al., PI-FACE DIFFERENTIATION IN MICHAEL REACTION TO THE ENONE GROUP ADJACENT TO THE (ETA-C5H5)MO(CO)2(PI-ALLYL) FRAGMENT - A NEW APPROACH TO THESTEREOSELECTIVE SYNTHESIS OF 2,3,4,5-TETRASUBSTITUTED-TETRAHYDROFURANCOMPOUNDS, Journal of the Chemical Society, Chemical Communications, (18), 1993, pp. 1391-1393
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
18
Year of publication
1993
Pages
1391 - 1393
Database
ISI
SICI code
0022-4936(1993):18<1391:PDIMRT>2.0.ZU;2-M
Abstract
The stereochemical outcome of the 1,4-addition of organocopper reagent s to (eta-C5H5)Mo(CO)2[eta3-1-(E)-C3H4COCH=CHR] compounds has been elu cidated; utilization of this reaction for synthesis of 2,3,4,5-tetrasu bstituted tetrahydrofuran is demonstrated.