SYNTHESIS AND CHARACTERIZATION OF A NOVEL DIOXYGEN COMPLEX OF MOLYBDENUM PORPHYRIN

Authors
TACHIBANA J IMAMURA T SASAKI Y
Citation
J. Tachibana et al., SYNTHESIS AND CHARACTERIZATION OF A NOVEL DIOXYGEN COMPLEX OF MOLYBDENUM PORPHYRIN, Journal of the Chemical Society, Chemical Communications, (18), 1993, pp. 1436-1438
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
18
Year of publication
1993
Pages
1436 - 1438
Database
ISI
SICI code
0022-4936(1993):18<1436:SACOAN>2.0.ZU;2-1
Abstract
A new molybdenum porphyrin dioxygen complex [Mo(VI)O(tmp)(O2)],dagger formed by the reversible reaction of [Mo(IV)O(tmp)] with dioxygen in a protic solvents at room temperature, is isolated and characterized by temperature-programmed desorption mass, IR, H-1 NMR, and UV-VIS spectr oscopy.