RAMAN-STUDY OF ALUMINUM-CHLORIDE DIMETHYLSULFONE SOLUTIONS

Authors
LEGRAND L TRANCHANT A MESSINA R ROMAIN F LAUTIE A
Citation
L. Legrand et al., RAMAN-STUDY OF ALUMINUM-CHLORIDE DIMETHYLSULFONE SOLUTIONS, Inorganic chemistry, 35(5), 1996, pp. 1310-1312
Citations number
33
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
5
Year of publication
1996
Pages
1310 - 1312
Database
ISI
SICI code
0020-1669(1996)35:5<1310:ROADS>2.0.ZU;2-4
Abstract
The Raman spectra of AlCl3-LiCl-dimethylsulfone mixtures with differen t molar compositions have been recorded as a solid (300 K) and as a me lt (400 K). In any case, only AlCl4- ion lines at 120, 179, and 347 cm (-1) were observed; we were unable to detect any other chloroaluminate species. Furthermore, some bands assigned to the Al[(CH3)(2)SO2](3+)( 3) octahedral coordination compound are evidence for a high AlCl3 cont ent.