SYNTHESIS AND MOLECULAR-STRUCTURE OF A NOVEL MONOCARBON HYDRIDORHODACARBORANE - O-2,7-(PPH(3))(2)-2-H-2-CL-1-(NME(3))-2,1-RHCB10H9

Authors
CHIZHEVSKY IT PISAREVA IV PETROVSKII PV BREGADZE VI DOLGUSHIN FM YANOVSKY AI STRUCHKOV YT HAWTHORNE MF
Citation
It. Chizhevsky et al., SYNTHESIS AND MOLECULAR-STRUCTURE OF A NOVEL MONOCARBON HYDRIDORHODACARBORANE - O-2,7-(PPH(3))(2)-2-H-2-CL-1-(NME(3))-2,1-RHCB10H9, Inorganic chemistry, 35(5), 1996, pp. 1386
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
5
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:5<1386:SAMOAN>2.0.ZU;2-U
Abstract
Syntheses of novel 18- and 16-electron monocarbon closo-rhodacarborane s derived from nido-B10H12-CNMe(3) are reported. so-2,7-(PPh(3))(2)-2- H-2Cl-1-(NMe(3))-2,1-RhCB10H9 (3) and closo-2-(PPh(3))-2-Cl-1-(NMe(3)) -2,1-RhCB10H10 (4) were prepared by heating Rh(PPh(3))(3)Cl with nido- B(10)H(12)CNMe(3) in methanol. The molecular structure of 3 was determ ined by X-ray diffraction and represents the first structurally charac terized hydride complex within the family of mononuclear icosahedral m onocarbon metallacarboranes.