SYNTHESIS, STRUCTURE, AND PROPERTIES OF YRIDYL)ETHYL]PYRIDINE-2,6-DICARBOXAMIDO)COPPER(II)

Authors
CHAVEZ FA OLMSTEAD MM MASCHARAK PK
Citation
Fa. Chavez et al., SYNTHESIS, STRUCTURE, AND PROPERTIES OF YRIDYL)ETHYL]PYRIDINE-2,6-DICARBOXAMIDO)COPPER(II), Inorganic chemistry, 35(5), 1996, pp. 1410
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Inorganic chemistry → ACNP
ISSN journal
00201669
Volume
35
Issue
5
Year of publication
1996
Database
ISI
SICI code
0020-1669(1996)35:5<1410:SSAPOY>2.0.ZU;2-1
Abstract
The Cu(II) complex of is(2-(2-pyridyl)ethyl)-pyridine-2,6-dicarboxamid e, a designed ligand with two amide moieties, has been isolated and st ructurally characterized. The copper center in this distorted square-p yramidal complex is coordinated to two deprotonated amido N donors and is situated 0.41 Angstrom above the mean basal plane. Such distortion results in a low A parallel to value of 154 G.