OXIDATION OF CARBON-MONOXIDE ON CU-CR-MN GAMMA-AL2O3 CATALYSTS FROM VARIOUS SOURCES/

Citation
Nm. Mardanova et al., OXIDATION OF CARBON-MONOXIDE ON CU-CR-MN GAMMA-AL2O3 CATALYSTS FROM VARIOUS SOURCES/, Kinetics and catalysis, 37(1), 1996, pp. 84-89
Citations number
13
Categorie Soggetti
Chemistry Physical
Journal title
ISSN journal
00231584
Volume
37
Issue
1
Year of publication
1996
Pages
84 - 89
Database
ISI
SICI code
0023-1584(1996)37:1<84:OOCOCG>2.0.ZU;2-B
Abstract
X-ray diffraction analysis, electron diffuse-reflectance spectroscopy, and kinetic measurements, conducted in a gradientless reactor, were u sed to study the effect of the introduction of active ingredients on t he composition and performance of the Cu-Cr-Mn/gamma-Al2O3 catalyst fo r CO oxidation. It was found that for the preparation of a highly effi cient catalyst, it is important to eliminate possible contacts between manganese and chromium ions in the bulk of the catalyst grain; this c an be accomplished by using an appropriate order of the introduction o f active ingredients into a ternary system when two of three component s are supported simultaneously (''binary-section'' method).