SYNTHESIS OF A BIS(CYCLOPENTADIENYL)LANTHANUM ARYL COMPLEX WITH A PSEUDOFACIALLY BOUND BIS(ORTHO)-CHELATING ARYLDIAMINE LIGAND - X-RAY STRUCTURE OF (ETA(5)-C5H5)(2)LA(C6H3(CH(2)NME(2))(2)-2,6)

Authors
HOGERHEIDE MP BOERSMA J SPEK AL VANKOTEN G
Citation
Mp. Hogerheide et al., SYNTHESIS OF A BIS(CYCLOPENTADIENYL)LANTHANUM ARYL COMPLEX WITH A PSEUDOFACIALLY BOUND BIS(ORTHO)-CHELATING ARYLDIAMINE LIGAND - X-RAY STRUCTURE OF (ETA(5)-C5H5)(2)LA(C6H3(CH(2)NME(2))(2)-2,6), Organometallics, 15(5), 1996, pp. 1505-1507
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
5
Year of publication
1996
Pages
1505 - 1507
Database
ISI
SICI code
0276-7333(1996)15:5<1505:SOABAC>2.0.ZU;2-O
Abstract
Reaction of Cp(3)La . THF with Li(C6H3{CH2-NMe(2)}(2)-2,6) in benzene gave the first crystallographically characterized lanthanum aryl compl ex (eta(5)-C5H5)(2)La-(C6H3{CH(2)NMe(2)}(2)-2,6), in which the bis(ort ho)-chelating aryldiamine ligand is bound in a pseudofacial ''Cp-like' ' fashion.