PDCL2-CATALYZED REDUCTION OF ORGANIC HALIDES BY TRIETHYLSILANE

Authors
BOUKHERROUB R CHATGILIALOGLU C MANUEL G
Citation
R. Boukherroub et al., PDCL2-CATALYZED REDUCTION OF ORGANIC HALIDES BY TRIETHYLSILANE, Organometallics, 15(5), 1996, pp. 1508-1510
Citations number
30
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
15
Issue
5
Year of publication
1996
Pages
1508 - 1510
Database
ISI
SICI code
0276-7333(1996)15:5<1508:PROOHB>2.0.ZU;2-W
Abstract
The palladium-catalyzed dehalogenation reaction of alkyl or aryl halid es with triethylsilane takes place, giving high yields under mild reac tion conditions. The efficiency of the reduction is similar for organi c chlorides, bromides, or iodides, and the presence of functionalities such as esters or ethers does not interfere with the outcome of the r eaction.