T. Cosgrove et al., SMALL-ANGLE NEUTRON-SCATTERING STUDIES OF SODIUM DODECYL-SULFATE INTERACTIONS WITH GELATIN .2. EFFECT OF TEMPERATURE AND PH, Journal of the Chemical Society. Faraday transactions, 92(4), 1996, pp. 595-599
Citations number
27
Categorie Soggetti
Chemistry Physical","Physics, Atomic, Molecular & Chemical
Structural perturbations and interactions between the anionic surfacta
nt sodium dodecyl sulfate (SDS) and the biopolymer and polyampholyte g
elatin, have been studied using small-angle neutron scattering. The ef
fects of temperature and changes in pH have been investigated. Althoug
h the physical properties of the systems change dramatically with temp
erature, from a gel at 25 degrees C to a fluid at 65 degrees C, the ef
fects on the structure over the dimensions probed by small-angle neutr
on scattering are rather weak. Changes in pH, which alter the net char
ge of the gelatin, lead to dramatic changes in the scattering for pure
gelatin solutions and for surfactant-gelatin mixtures.