ACYLATION OF UNSATURATED HALIDES, ALCOHOLS, ESTERS AND KETONES

Citation
D. Barbry et al., ACYLATION OF UNSATURATED HALIDES, ALCOHOLS, ESTERS AND KETONES, Synthetic communications, 23(19), 1993, pp. 2647-2658
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00397911
Volume
23
Issue
19
Year of publication
1993
Pages
2647 - 2658
Database
ISI
SICI code
0039-7911(1993)23:19<2647:AOUHAE>2.0.ZU;2-3
Abstract
treatment of the title compounds with acyl halide and Lewis acid affor ds unsaturated ketones (mainly alpha-beta with aluminium chloride, sel ectively beta-gamma with silver tetrafluoroborate). Reduction of the a lkenyl group gives polyfunctional ketones.