A. Sander et al., IRON CORROSION IN DRINKING-WATER DISTRIBUTION-SYSTEMS - THE EFFECT OFPH, CALCIUM AND HYDROGEN CARBONATE, Corrosion science, 38(3), 1996, pp. 443-455
The corrosion of iron in synthetic drinking water has been studied thr
ough potentiodynamic sweeps and coupon tests. Corrosion rate follows a
reversed proportional dependence on the logarithm of the free carbon
dioxide content (the sum of protonated carbonic acid and dissolved car
bon dioxide). In water with low total carbonate concentrations the add
ition of calcium ions decreases the corrosion rate. In waters with mod
erate and high total carbonate content no dependence on the calcium co
ncentration is observed.