SELECTIVITY IN BROMINATION OF ANILINE AND N-SUBSTITUTED ANILINES ENCAPSULATED IN BETA-CYCLODEXTRIN

Authors
VELUSAMY P PITCHUMANI K SRINIVASAN C
Citation
P. Velusamy et al., SELECTIVITY IN BROMINATION OF ANILINE AND N-SUBSTITUTED ANILINES ENCAPSULATED IN BETA-CYCLODEXTRIN, Tetrahedron, 52(10), 1996, pp. 3487-3496
Citations number
32
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
10
Year of publication
1996
Pages
3487 - 3496
Database
ISI
SICI code
0040-4020(1996)52:10<3487:SIBOAA>2.0.ZU;2-F
Abstract
In contrast to the conventional bromination, aniline and N-methylanili ne encapsulated in beta-Cyclodextrin (beta-CD) give ortho-bromoaniline and para-bromo-N-methylaniline respectively in larger yield. The resu lts are explained on the basis of mode of complexation between beta-CD and anilines.