SYNTHETIC APPLICATIONS OF 2-(1,3-DITHIAN-2-YL)INDOLES .6. SYNTHESIS OF 20-EPIDASYCARPIDONE

Authors
FORNS P DIEZ A RUBIRALTA M SOLANS X FONTBARDIA M
Citation
P. Forns et al., SYNTHETIC APPLICATIONS OF 2-(1,3-DITHIAN-2-YL)INDOLES .6. SYNTHESIS OF 20-EPIDASYCARPIDONE, Tetrahedron, 52(10), 1996, pp. 3563-3574
Citations number
17
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
10
Year of publication
1996
Pages
3563 - 3574
Database
ISI
SICI code
0040-4020(1996)52:10<3563:SAO2.S>2.0.ZU;2-L
Abstract
20-Epidasycarpidone (10) and its N-benzyl analogue 9 have been synthes ized via a conjugate addition of 2-(1,3-dithian-2-yl)indole (6) and 3- ethyl-Delta(3)-piperidein-2-ones 7 and 8, respectively. The transforma tion of 20-epidasycarpidone to 20-epiuleine (11) has been carried out as described in the literature in order to corroborate the structural assignments.