CYCLOADDITION OF HOMOCHIRAL IMIDAZOLINIUM YLIDES - A ROUTE TO OPTICALLY-ACTIVE PYRROLOIMIDAZOLES

Authors
JONES RCF HOWARD KJ SNAITH JS
Citation
Rcf. Jones et al., CYCLOADDITION OF HOMOCHIRAL IMIDAZOLINIUM YLIDES - A ROUTE TO OPTICALLY-ACTIVE PYRROLOIMIDAZOLES, Tetrahedron letters, 37(10), 1996, pp. 1707-1710
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
10
Year of publication
1996
Pages
1707 - 1710
Database
ISI
SICI code
0040-4039(1996)37:10<1707:COHIY->2.0.ZU;2-D
Abstract
The synthesis of either enantiomer of 1-benzyl-4-phenyl-2-imidazoline from phenylglycine is described. 'One-pot' generation and enantioselec tive 1,3-dipolar cycloaddition of homochiral azomethine ylides prepare d from these imidazolines with a range of alkene dipolarophiles afford s optically active hexahydropyrroloimidazole adducts.