THE REACTIONS OF ARYL ACRYLATES UNDER BAYLIS-HILLMAN CONDITIONS

Citation
P. Perlmutter et al., THE REACTIONS OF ARYL ACRYLATES UNDER BAYLIS-HILLMAN CONDITIONS, Tetrahedron letters, 37(10), 1996, pp. 1715-1718
Citations number
12
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
ISSN journal
00404039
Volume
37
Issue
10
Year of publication
1996
Pages
1715 - 1718
Database
ISI
SICI code
0040-4039(1996)37:10<1715:TROAAU>2.0.ZU;2-8
Abstract
The use of aryl acrylates in the Baylis-Hillman reaction is reported. In contrast to their alkyl counterparts these acrylates react very rap idly with aldehydes, often yielding cyclic products arising from react ion of the initial adduct with a second molecule of aldehyde.