Reductive splitting experiments demonstrated a high degree of preserva
tion of typical lignin structures in humic substances that are the maj
or products of lignin environmental biodegradation. Atomic force micro
scopy and scanning tunneling microscopy provided a comparative analysi
s of the morphological character of lignin, lignin model compounds, an
d humic substances sorbed on organic and mineral surfaces. Chemical an
d morphological similarity between lignins and humic substances sugges
ts the use of waste lignins as soil improvement agents.