REACTION OF 1,2-DIKETONES WITH N,N-DIMETHYLCYANAMIDE IN THE PRESENCE OF TITANIUM(IV) CHLORIDE

Authors
MAZIK M BOESE R SUSTMANN R
Citation
M. Mazik et al., REACTION OF 1,2-DIKETONES WITH N,N-DIMETHYLCYANAMIDE IN THE PRESENCE OF TITANIUM(IV) CHLORIDE, Tetrahedron, 52(11), 1996, pp. 3939-3946
Citations number
28
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
52
Issue
11
Year of publication
1996
Pages
3939 - 3946
Database
ISI
SICI code
0040-4020(1996)52:11<3939:RO1WNI>2.0.ZU;2-Q
Abstract
In the presence of titanium(IV) chloride 1,2-diketones undergo [2+2] c ycloaddition to N,N-dimethylcyanamide with subsequent ring opening to bamoyl-2,3-disubstitute-1-oxa-4-aza-1,3-butadienes 5 and bamoyl)-2,3-d isubstituted-1,4-diaza-1,3-butadienes 10.