AN ASYMMETRIC-SYNTHESIS OF (-ISONITRAMINE BY TRIPLE ALLYLIC STRAIN-CONTROLLED INTRAMOLECULAR S(N)2' ALKYLATION())

Authors
KIM D CHOI WJ HONG JY PARK IY KIM YB
Citation
D. Kim et al., AN ASYMMETRIC-SYNTHESIS OF (-ISONITRAMINE BY TRIPLE ALLYLIC STRAIN-CONTROLLED INTRAMOLECULAR S(N)2' ALKYLATION()), Tetrahedron letters, 37(9), 1996, pp. 1433-1434
Citations number
26
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
37
Issue
9
Year of publication
1996
Pages
1433 - 1434
Database
ISI
SICI code
0040-4039(1996)37:9<1433:AAO(BT>2.0.ZU;2-2
Abstract
The spirocyclic alkaloid (+)-isonitramine (1) has been synthesized in a stereo selective manner utilizing a novel 'triple allylic strain-con trolled' intramolecular lactam enolate S(N)2' alkylation.