R. Fischer et al., GRAIN-SIZE DEPENDENCE OF REMANENCE AND COERCIVE FIELD OF ISOTROPIC NANOCRYSTALLINE COMPOSITE PERMANENT-MAGNETS, Journal of magnetism and magnetic materials, 153(1-2), 1996, pp. 35-49
Micromagnetic calculations using a finite element technique are useful
to investigate magnetization processes in nanocrystalline ferromagnet
ic materials. In particular numerical calculations reveal the microstr
uctural conditions required for high remanence and high coercivity iso
tropic permanent magnets. composite materials of Nd2Fe14B and alpha-Fe
are excellent candidates for such high performance permanent magnets,
The soft magnetic alpha-Fe grains cause a large spontaneous magnetiza
tion and the hard magnetic grains induce a large coercive field, provi
ded that both phases are strongly exchange coupled. The numerical inve
stigations on realistic three-dimensional grain arrangements suggest a
n optimal microstructure consisting of small soft magnetic grains (D a
pproximate to 10 nm, V-soft approximate to 40%) embedded between hard
magnetic grains with a mean grain diameter of about D approximate to 2
0 nm. Additionally, a microstructure with regular shaped grains improv
es the magnetic properties.