(ETA(4)-CYCLOOCTA-1,5-DIENE)(2-PYRIDINETHIOLATO N-OXIDE-KAPPA-O, KAPPA-S)IRIDIUM(I)

Authors
THERON M PURCELL W BASSON SS
Citation
M. Theron et al., (ETA(4)-CYCLOOCTA-1,5-DIENE)(2-PYRIDINETHIOLATO N-OXIDE-KAPPA-O, KAPPA-S)IRIDIUM(I), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 336-338
Citations number
17
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
2
Pages
336 - 338
Database
ISI
SICI code
0108-2701(1996)52:<336:(NK>2.0.ZU;2-N
Abstract
The title compound, [Ir(C5H4NOS)(C8H12)], contains an Ir atom in an ap proximately square-planar environment if we consider the coordination plane formed by the midpoints of the double bonds of the cyclooctadien e ligand together with the S and O atoms [deviation from least-squares plane is 0.01 (5)Angstrom]. The S,O-ligand is also planar and the fiv e-membered chelate ring has a bite angle of 84.4 (3)degrees at the Ir atom. Bond distances are Ir-S = 2.270 (4), Ir-O = 2.031 (9) and averag e Ir-C(olefinic) = 2.11 (2)Angstrom.