HYLPROPANE-1,2-DIAMINE)DIISOTHIOCYANATOCADMIUM(II)

Authors
PARIYA C CHAUDHURI NR SETH S DAS A
Citation
C. Pariya et al., HYLPROPANE-1,2-DIAMINE)DIISOTHIOCYANATOCADMIUM(II), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 358-360
Citations number
13
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
2
Pages
358 - 360
Database
ISI
SICI code
0108-2701(1996)52:<358:H>2.0.ZU;2-7
Abstract
In the complex [Cd(NCS)(2)(C7H18N2)(2)], the Cd atom lies on an invers ion centre and has a distorted octahedral environment consisting of fo ur amine N atoms from two bidentate N-1-isopropyl-2-methylpropane-1,2- diamine (N-N) ligands [Cd-N(primary) = 2.362(3) Angstrom, Cd-N(seconda ry) = 2,400(3) Angstrom] and two N atoms from two isothiocyanato group s [Cd-N = 2.378(5) Angstrom]. The conformation of the diamine chelate rings is delta lambda. Molecules are linked by N-H ... S hydrogen bond s(N ... S 3.665 Angstrom.