THYLDITHIOCARBAMATO)(4-METHOXYPHENYL)TELLURIUM(IV) DICHLOROMETHANE HEMISOLVATE, P-MEOC(6)H(4)TE(ME(2)NCS(2))(2)BR.0.5CH(2)CL(2)

Authors
HUSEBYE S KUDIS S LINDEMAN SV
Citation
S. Husebye et al., THYLDITHIOCARBAMATO)(4-METHOXYPHENYL)TELLURIUM(IV) DICHLOROMETHANE HEMISOLVATE, P-MEOC(6)H(4)TE(ME(2)NCS(2))(2)BR.0.5CH(2)CL(2), Acta crystallographica. Section C, Crystal structure communications, 52, 1996, pp. 429-432
Citations number
7
Categorie Soggetti
Crystallography
Journal title
Acta crystallographica. Section C, Crystal structure communications → ACNP
ISSN journal
01082701
Volume
52
Year of publication
1996
Part
2
Pages
429 - 432
Database
ISI
SICI code
0108-2701(1996)52:<429:TDH>2.0.ZU;2-F
Abstract
The structure of the title Te-IV complex, C13H19BrN2OS4Te.0.45(CH2Cl2) , is pentagonal bipyramidal with four S atoms [Te-S 2.623(1)-2.717(1) Angstrom] and the Br atom [Te-Br 2.890(1) Angstrom] in equatorial posi tions. The p-methoxyphenyl group is axial [Te-C 2.145 (3) Angstrom] an d the second axial position seems to be occupied by a dithiocarbamate group of a neighbouring molecule acting as a pi ligand [Te ... C 3.751 (3) Angstrom, C-Te ... C 170.2 (1)degrees], so that molecules are join ed into centrosymmetric associations by this secondary coordination.