Q. Liao et E. Herbst, CALCULATIONS OF THE LOW-TEMPERATURE PRESSURE BROADENING OF HCO-LINES BY H-2( ROTATIONAL SPECTRAL), The Journal of chemical physics, 104(11), 1996, pp. 3956-3961
Calculations on the pressure broadening by H-2 of HCO+ rotational spec
tral lines have been performed in the temperature range 11-300 K. Rece
nt low temperature measurements of the pressure broadening of the J=3-
2 line at 11-30 K are reproduced to within 10-20% by the results of a
capture theory. The results of Anderson theory in this temperature ran
ge, on the other hand, are low by a factor of up to approximate to 3 c
ompared with experiment. A hybrid method is proposed, which converges
to the capture theory at low temperatures and the Anderson theory at h
igh temperatures. (C) 1996 American Institute of Physics.