CALCULATION OF 2P(4)(P-3)NL(L=S,D) RYDBERG SPECTRA OF THE FLUORINE ISOELECTRONIC SEQUENCE

Authors
Citation
Xz. Qian et Zw. Wang, CALCULATION OF 2P(4)(P-3)NL(L=S,D) RYDBERG SPECTRA OF THE FLUORINE ISOELECTRONIC SEQUENCE, Zeitschrift fur Physik. D, Atoms, molecules and clusters, 36(2), 1996, pp. 93-99
Citations number
10
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
ISSN journal
01787683
Volume
36
Issue
2
Year of publication
1996
Pages
93 - 99
Database
ISI
SICI code
0178-7683(1996)36:2<93:CO2RSO>2.0.ZU;2-T
Abstract
The basic structure parameters of 2p(4)(P-3)ns and 2p(4)(P-3)nd (J = 1 /2, 3/2 and 5/2) Rydberg spectra for the fluorine isoelectronic sequen ce from FI to NiXX, as functions of effective nuclear charge, are calc ulated by using the eigenchannel quantum-defect theory. The results ca n be interpreted in terms of the variations of electrostatic and spin- orbit interactions along the sequence. A vast amount of basic atomic d ata can be obtained with these parameters as input. Some numerical exa mples are given, in which our results are in perfect agreement with ex perimental.