Xz. Qian et Zw. Wang, CALCULATION OF 2P(4)(P-3)NL(L=S,D) RYDBERG SPECTRA OF THE FLUORINE ISOELECTRONIC SEQUENCE, Zeitschrift fur Physik. D, Atoms, molecules and clusters, 36(2), 1996, pp. 93-99
The basic structure parameters of 2p(4)(P-3)ns and 2p(4)(P-3)nd (J = 1
/2, 3/2 and 5/2) Rydberg spectra for the fluorine isoelectronic sequen
ce from FI to NiXX, as functions of effective nuclear charge, are calc
ulated by using the eigenchannel quantum-defect theory. The results ca
n be interpreted in terms of the variations of electrostatic and spin-
orbit interactions along the sequence. A vast amount of basic atomic d
ata can be obtained with these parameters as input. Some numerical exa
mples are given, in which our results are in perfect agreement with ex
perimental.