Studies have been made of the gelation of mixtures of iota and kappa c
arrageenan. Differential scanning calorimetry (DSC) studies suggest th
at the iota and kappa components gel independently of each other. The
DSC data conflict with evidence presented for the currently accepted D
omain model for carrageenan gelation (Morris, E.R., Rees, D.A. and Rob
inson, G.J. J. Mel. Biol. 1980; 138: 349). In particular, the present
data suggest that iota carrageenan gels show thermoreversible setting
and melting behaviour associated with the coil-helix transition. Analy
sis of rheological data favours an interpenetrating network (IPN) mode
l for gelation of the mixtures.