A. Fritz et Mh. Pahl, LAW OF SUBSTANCE SEPARATION ON CROSS-FLOW FILTRATION IN TURBULENT-FLOW, Chemical engineering & technology, 19(1), 1996, pp. 11-19
Cross-flow filtration is a filtration process for separation of a disp
erse phase from liquids. Suspension flows tangentially to a membrane a
nd the filtrate is drawn off perpendicular to the direction of flow. F
ormation of a filter cake on the membrane is thus prevented, reduced,
or its composition modified. The principle of the separation is based
on two opposing effects: on the one hand, the particles are transporte
d by the filtration flux to the membrane where they cause an increase
in concentration; on the other hand, concentration differences are aga
in reduced by the turbulence of the cross-flow and by Brownian motion
of the particles. The two mechanisms compete with each other and depen
d upon particle size in different ways. An energetic comparison of the
two effects yields the separation law of cross-flow filtration asa st
eady state solution of the Fokker-Planck equation. The separation law
has an exponential form and assigns each particle size a separation pr
obability with which it reaches the membrane. Once on the membrane the
particles may form a filter cake, flow through the pores or return to
the bulk flow. If the particles remain on the membrane the ranges of
layer-free and cake-forming filtration can be calculated from the hydr
odynamic and geometric conditions of the cross-flow filter. Convention
al cake filtration is regarded as limiting case. In continuous cross-f
low filtration processes a low separation probability through the filt
ration pressure on selection of the filter medium resistance.