When comet C/1995 O1 (Hale-Bopp) was discovered(1), at a distance of s
even astronomical units from the Sun, it was more than one hundred tim
es brighter than comet Halley at the same distance. A comet's brightne
ss is derived from the reflection of sunlight from dust grains driven
away from the nucleus by the sublimation of volatile ices. Near the Su
n, sublimation of water ice (a main constituent of comet nuclei) is th
e source of cometary activity; but at its current heliocentric distanc
e, Hale-Bopp is too cold for this process to operate. Other comets hav
e shown activity at large distances(2), and in the case of comet Schwa
ssmann-Wachmann 1, carbon monoxide has been detected in quantities suf
ficient to generate its observed coma(3,4). Here we report the detecti
on of CO emission from Hale-Bopp, at levels indicating a very large ra
te of outgassing. Several other volatile species were searched for, bu
t not detected. Sublimation of CO therefore appears to be responsible
for the present activity of this comet, and we anticipate that future
observations will reveal the onset of sublimation of other volatile sp
ecies as the comet continues its present journey towards the Sun.