Wj. Cumming et Ra. Gaudiana, THE EFFECT OF FLUOROCARBON TAILS ON THE PHASE-BEHAVIOR OF SOME SCHIFFS BASE LIQUID-CRYSTALS, Liquid crystals, 20(3), 1996, pp. 283-286
Several new liquid crystalline compounds comprising Schiff's-base cinn
amate cores and fluorocarbon alkoxy tails of varying lengths have been
synthesized and characterized. The thermal properties of these materi
als are compared to those of their hydrocarbon analogues. The results
show that fluorination stabilizes the crystalline phase, quite unexpec
tedly destabilizes the S-C phase, and for two of the compounds produce
s extraordinarily stable S-A phases.