Lv. Natarajan et al., ELECTROOPTICAL SWITCHING CHARACTERISTICS OF VOLUME HOLOGRAMS IN POLYMER-DISPERSED LIQUID-CRYSTALS, Journal of nonlinear optical physics and materials, 5(1), 1996, pp. 89-98
Electrically switchable volume holograms lead to the possibility of re
al-time electrooptical control of diffractive optic components. We rep
ort here on the development of a novel photopolymer-liquid crystal com
posite material system for writing in a fast single step, high diffrac
tion efficiency volume holograms, capable of switching in applied elec
tric fields of low voltage. Switching of a first-order Bragg diffracte
d beam into the zero-order with an applied field of similar to 10 V/mu
m was observed. With the addition of a surfactant to our pre-polymer
syrup, we observed lowering of the switching fields to similar to 5 V/
mu m. We report response times for switching and relaxation in the ord
er of microseconds. Low voltage, high resolution scanning electron mic
roscopy studies show that the Bragg gratings formed consist of periodi
c polymer dispersed liquid crystal planes. The addition of surfactant
leads to formation of very uniform small (20-40 nm) nematic droplets.
A simple model based on the shape of the liquid crystal droplets was a
pplied to explain the switching fields and response times.