The barium releases from the CRRES satellite have provided an opportun
ity for verifying theoretically calculated barium ion and neutral emis
sion rates. Spectra of the five Caribbean releases in the summer of 19
91 were taken with a spectrograph on board a U.S. Air Force jet aircra
ft. Because the line of sight release densities are not known, only re
lative rates could be obtained. The observed relative rates agree well
with the theoretically calculated rates and, together with other obse
rvations, confirm the earlier detailed theoretical emission rates. The
calculated emission rates can thus with good accuracy be used with ph
otometric observations. It has been postulated that charge exchange be
tween neutral barium and oxygen ions represents a significant source f
or ionization. If so, it should be associated with emissions at 4957.1
5 angstrom and 5013.00 angstrom, but these emissions were not detected
.