FROM GAS-PHASE TO CONDENSED-PHASE - TOWARDS METAPHOSPHATE GENERATION IN SOLUTION

Authors
BANKS MR CADOGAN JIG GOSNEY I HODGSON PKG KILGOUR D RODGER DR
Citation
Mr. Banks et al., FROM GAS-PHASE TO CONDENSED-PHASE - TOWARDS METAPHOSPHATE GENERATION IN SOLUTION, Phosphorus, sulfur and silicon and the related elements, 76(1-4), 1993, pp. 297-300
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
76
Issue
1-4
Year of publication
1993
Pages
297 - 300
Database
ISI
SICI code
1042-6507(1993)76:1-4<297:FGTC-T>2.0.ZU;2-8
Abstract
Based on attempts to generate methyl metaphophate in solution by therm al fragmentation of a cyclic pyrocarbonate phosphate, it has emerged t hat reaction of methyl dichlorophosphate with anhydrous potassium hydr ogen carbonate serves as an alternative approach as proven by trapping with styrene oxide to form a 1,3,2-dioxaphospholane.