P=SI-BONDS AND AS=SI-BONDS AS BUILDING-BLOCKS FOR UNUSUAL PHOSPHORUS-SILICON-HETEROCYCLES AND ARSENIC-SILICON-HETEROCYCLES

Authors
DRIESS M PRITZKOW H
Citation
M. Driess et H. Pritzkow, P=SI-BONDS AND AS=SI-BONDS AS BUILDING-BLOCKS FOR UNUSUAL PHOSPHORUS-SILICON-HETEROCYCLES AND ARSENIC-SILICON-HETEROCYCLES, Phosphorus, sulfur and silicon and the related elements, 76(1-4), 1993, pp. 317-320
Citations number
5
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
76
Issue
1-4
Year of publication
1993
Pages
317 - 320
Database
ISI
SICI code
1042-6507(1993)76:1-4<317:PAAABF>2.0.ZU;2-K
Abstract
The high-yield access to new stable, activated phosphanylidensilanes a nd the first arsanylidensilane enabled us to investigate the reactivit y of these very reactive compounds. Cycloaddition and oxidation reacti ons leads to new classes of heterocycles. For example, the first azaph osphasiliridine as well as arsaazasiliridine derivative has been chara cterized by X ray crystal structure determination.