SYNTHESIS AND REACTIVITY OF NEW GERMAPHOSPHENES AND STANNAPHOSPHENES

Authors
RANAIVONJATOVO H ESCUDIE J COURET C RODI AK SATGE J
Citation
H. Ranaivonjatovo et al., SYNTHESIS AND REACTIVITY OF NEW GERMAPHOSPHENES AND STANNAPHOSPHENES, Phosphorus, sulfur and silicon and the related elements, 76(1-4), 1993, pp. 321-324
Citations number
4
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
76
Issue
1-4
Year of publication
1993
Pages
321 - 324
Database
ISI
SICI code
1042-6507(1993)76:1-4<321:SARONG>2.0.ZU;2-K
Abstract
New stable compounds with a germanium (or a tin)-phosphorus double bon d have been prepared respectively by a one step reaction between a lit hiophosphide and a difluorogermane, or by dehydrofluorination of the c orresponding fluorostannylphosphine with tert-butyllithium. Various ty pes of cycloadditions ([2+2], [2+3] and [2+4]) have been observed with aldehydes, nitrones and alpha-ethylenic aldehydes and ketones.