Radiative recombination in n-Hg1-xCdxSe (0.2 less than or equal to x l
ess than or equal to 0.32) in the temperature range 4.2-77 K and in ma
gnetic fields up to 8 T was investigated. The concentration N-d-N-A Of
uncontrollable impurities was equal to (2-6) x 10(16) cm(-3). The pho
toluminescence spectra of n-Hg1-xCdxSe at 4.2 K in the absence of a ma
gnetic field have a three-band structure. The observed emission bands
were identified on the basis of integrated photoluminescence and photo
electric investigations and the effects of the temperature and a magne
tic field: The short-wavelength A band is due to excitons bound on don
or impurities, the B band is due to an exciton bound on composition fl
uctuations, and the long-wavelength C band is due to donor-acceptor re
combination. The energy position of the donor was at 1.9 meV and the a
cceptor states were at 90 and 8 meV. (C) 1996 American Institute of Ph
ysics.