A comprehensive study of the annealing behavior of magneto-optical dis
c substrates was performed, offering important insight into the origin
of birefringence, The lateral birefringence is a result of the flow-i
nduced molecular orientation in the skin layers generated in the mold
filling stage, and the cooling-induced energy-elastic stresses generat
ed inside and outside the mold. Cooling-induced energy-elastic birefri
ngence relaxes quickly, and consequently the flow-induced birefringenc
e with a radial dependence of decrease at the outer radius becomes pre
dominant after annealing below the glass transition temperature. The a
nnealing behavior of the vertical birefringence follows a Kohlrausch-W
illiams-Watts-type relaxation. The results serve as a predictive tool
for similar substrates.