Ai. Afifi et al., THE ARYL ETHER BOND REACTIONS WITH H-DONOR SOLVENTS - GUAIACOL AND TETRALIN IN THE PRESENCE OF CATALYSTS, Fuel, 75(4), 1996, pp. 509-516
The effect of homogenous catalysis, Fe and Ru, on the conversion of gu
aiacol in tetralin to catechol and phenol has been investigated as a m
odel for the behaviour of the aryl-oxy linkage that is found in wood,
peat and younger coals. In the absence of catalyst and at low ratios o
f guaiacol to tetralin, the primary product is catechol. Kinetic analy
sis has confirmed that the rate constant for this primary and rate det
ermining step is given by an Arrhenius pre-exponential factor of 10(13
.8) s(-1) With an activation energy of 215 kJ mol(-1). The activation
energy found is in good agreement with those of other investigators an
d lies between the values proposed for homolytic fission (>240 kJ mol(
-1)) and for a concerted or pericyclic reaction (188 kJ mol(-1)). In t
he presence of catalysts the rate is not changed; however, the yield o
f a secondary product phenol is increased with both Fe and Ru. Separat
e experiments confirmed that the selectivity of catechol to phenol con
version was markedly increased in the presence of these catalysts. The
re is strong evidence for the formation of catecholato-iron complexes
and this suggests that in pyrolysis and liquefaction of biomass and yo
ung coals there may well be a role for homogeneous catalysts in direct
ing the product slate towards useful intermediate chemicals such as ph
enols.