TRIARYLPHOSPHINES - MOLECULAR-GEOMETRY, ANODIC BEHAVIOR AND ESR STUDYOF THE RADICAL CATIONS

Authors
REDOUANE N VILA F CHALIER F GRONCHI G TORDO P
Citation
N. Redouane et al., TRIARYLPHOSPHINES - MOLECULAR-GEOMETRY, ANODIC BEHAVIOR AND ESR STUDYOF THE RADICAL CATIONS, Phosphorus, sulfur and silicon and the related elements, 77(1-4), 1993, pp. 653-656
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Phosphorus, sulfur and silicon and the related elements → ACNP
ISSN journal
10426507
Volume
77
Issue
1-4
Year of publication
1993
Pages
653 - 656
Database
ISI
SICI code
1042-6507(1993)77:1-4<653:T-MABA>2.0.ZU;2-3
Abstract
A large series of triarylphosphines has been prepared and their geomet ry was studied by force field calculations. A very good agreement was found between the calculated and experimental (X Ray) geometries. The oxidation potentials were determined by electrochemical techniques and the corresponding cations were studied by ESR. Both the oxidation pot entials and the ESR features were shown to depend strongly on the mole cular geometry.