Am. Hadian et Ral. Drew, STRENGTH AND MICROSTRUCTURE OF SILICON-NITRIDE CERAMICS BRAZED WITH NICKEL-CHROMIUM-SILICON ALLOYS, Journal of the American Ceramic Society, 79(3), 1996, pp. 659-665
Joining of sintered Si3N4 was performed using a high-temperature brazi
ng technique. Ni-based brazing alloys having the same Ni:Cr ratio as A
WS BNi-5 (Ni . 18Cr . 19Si (at.%)) but different Si content were used
as the brazing filler metals. Joining experiments were performed at 12
20 degrees C under a N-2 partial pressure of 15 Pa for different times
between 5 to 15 min. The highest room-temperature four-point bend str
ength of the joints was 115 MPa, whereas 220 MPa was achieved when the
joints were tested at 900 degrees C. The high strength of the experim
ental joints was attributed to the reduction in residual stresses and
formation of a CrN reaction layer at the ceramic/filler metal interfac
e.