THE CONFORMATION OF 3-ENDO-ARYLMETHYLISOBORNYL ESTERS

Authors
SEO BI SUH IH JENSEN WP LEWIS DE WALL LK JACOBSON RA
Citation
Bi. Seo et al., THE CONFORMATION OF 3-ENDO-ARYLMETHYLISOBORNYL ESTERS, Tetrahedron : asymmetry, 3(3), 1992, pp. 367-370
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Tetrahedron : asymmetry → ACNP
ISSN journal
09574166
Volume
3
Issue
3
Year of publication
1992
Pages
367 - 370
Database
ISI
SICI code
0957-4166(1992)3:3<367:TCO3E>2.0.ZU;2-Q
Abstract
The conformation of the benzyl group in 3-endo-benzylisobornyl esters depends on the nature of the ester group, and changes into a position close to coplanar with the ester group as the carbonyl group of the es ter becomes conjugated. The potential use of these alcohols as chiral auxiliaries in asymmetric synthesis is addressed.