L. Daweritz et al., TAILORING OF SI DOPING LAYERS IN GAAS DURING MOLECULAR-BEAM EPITAXY, Physica status solidi. b, Basic research, 194(1), 1996, pp. 127-144
For Si delta-like doping of GaAs lateral ordering processes and segreg
ation in growth direction have been investigated in real time by monit
oring longe-range and short-range ordering effects using reflection hi
gh-energy electron diffraction (RHEED) and reflectance anisotropy spec
troscopy (RAS). When Si is supplied in pulses to GaAs(001) distinct or
dering processes occur which are promoted by misorientation steps on t
he vicinal surface. The incorporation of Si atoms on Ga sites in a sin
gle plane can be completed to a high degree. The depth profile of the
electron concentration is closely related to Si segregation during GaA
s overgrowth. In the case of a doping layer of extremely high coverage
it shows a minimum at the centre of the doping spike. For samples gro
wn on vicinal GaAs(001) surfaces under conditions favourable for wire-
like Si incorporation a considerable enhancement of the exciton photol
uminescence (PL) intensity and decay time has been found.