Decoration of glass using enamel is interesting for hollow glassware a
s well as for flat glass sheets. Laser radiation can be used advantage
ously to increase the temperature of the product locally. The reaction
s which take place during CO2 laser heat treatment of a conventional P
bO-containing frit are discussed intensely. Pyrometrical temperature m
easurements accompany the experiments to investigate the temperature d
evelopment during CO2 laser irradiation. At temperatures above T-g opt
imal results concerning low surface roughness, high brightness and int
ensive colouration are obrained without deformation of the shape of th
e product. Very promising results show that higher temperatures can be
achieved by laser application and therefore PbO-free frits can be use
d.