THE PROGRAMMED ASSEMBLY-CONTROLLED DISASSEMBLY OF [2]ROTAXANES AS A STRATEGY IN SYNTHESIS - THE PREPARATION OF A CHEMICAL SENSOR FOR CO2

Authors
JOHNSTON AG LEIGH DA MURPHY A SMART JP
Citation
Ag. Johnston et al., THE PROGRAMMED ASSEMBLY-CONTROLLED DISASSEMBLY OF [2]ROTAXANES AS A STRATEGY IN SYNTHESIS - THE PREPARATION OF A CHEMICAL SENSOR FOR CO2, Bulletin des Societes chimiques belges, 105(10-11), 1996, pp. 721-727
Citations number
16
Categorie Soggetti
Chemistry
Journal title
Bulletin des Societes chimiques belges → ACNP
ISSN journal
00379646
Volume
105
Issue
10-11
Year of publication
1996
Pages
721 - 727
Database
ISI
SICI code
0037-9646(1996)105:10-11<721:TPADO[>2.0.ZU;2-F
Abstract
The templated assembly of a macrocycle around a thread to form a [2]ro taxane, followed by its quantitative disassembly into topologically si mple components, allows the facile preparation and chromatography-free isolation of 1 a macrocycle that had proven impossible to obtain by c onventional means because of its extremely poor solubility in most org anic solvents.