STEREOCONTROLLED INTRODUCTION OF DEUTERIUM ATOMS INTO A PHYTOALEXIN ELICITOR-ACTIVE BETA-D-GLUCOHEXAOSIDE

Authors
HONG N NAKAHARA Y OGAWA T
Citation
N. Hong et al., STEREOCONTROLLED INTRODUCTION OF DEUTERIUM ATOMS INTO A PHYTOALEXIN ELICITOR-ACTIVE BETA-D-GLUCOHEXAOSIDE, Proceedings of the Japan Academy. Series B Physical and biological sciences, 69(3), 1993, pp. 55-60
Citations number
21
Categorie Soggetti
Multidisciplinary Sciences",Biology
Journal title
Proceedings of the Japan Academy. Series B Physical and biological sciences → ACNP
ISSN journal
03862208
Volume
69
Issue
3
Year of publication
1993
Pages
55 - 60
Database
ISI
SICI code
0386-2208(1993)69:3<55:SIODAI>2.0.ZU;2-I
Abstract
Stereocontrolled deuterium labelling of phytoalexin elicitor-active be ta-D-glucohexaoside 2 was executed by employing a stereospecifically d euterated D-glucose derivative 11 as a starting material. As a result, unambiguous assignment of the anomeric signals in H-1-NMR of compound 2 was achieved by use of the deuterated compounds 3, 4, and 5.