Planar optical waveguides are an attractive tool for use in analytical
chemistry and spectroscopy. Although similar to fiber optics, planar
waveguides have been slow to be commercially accepted due to the diffi
culty of coupling light into the guide. Generally, prism coupling is t
he method of choice in the laboratory, as efficiencies approaching 80%
can be reached. However, prisms are impractical for routine use for s
everal reasons: expensive positioning equipment is required, coupled p
ower is sensitive to environmental fluctuations, and prism coupling pr
ohibits the fabrication of a truly planar device. The use of thin grat
ings on the surface of the waveguide allows for a two-dimensional stru
cture to be maintained, while providing enough efficiency to be useful
as a sensor. Our research efforts focus on developing a technique to
make inexpensive, reproducible gratings that are easy to fabricate. By
chemically modifying the surface of a commercial grating with a suita
ble release agent, it is possible to emboss replica gratings onto a va
riety of waveguide types. The fabrication of embossed gratings will be
described, and their performance on glass, ion-diffused, polymer, and
semiconductor waveguides will be presented.