We demonstrate the quality factor Q = (0.8 +/- 0.1) X 10(10) of whispe
ring-gallery modes in fused-silica microspheres at 633 nm, close to th
e ultimate level determined by fundamental material attenuation as mea
sured in optical fibers. The lifetime of ultimate Q is limited by adso
rption of atmospheric water. Monitoring of adsorption kinetics with su
bmonolayer sensitivity by Q factors and frequencies of whispering-gall
ery modes is demonstrated. The possibility of supermaterial Q's owing
to intrinsic suppression of scattering losses in micropheres is discus
sed. (C) 1996 Optical Society of America