A systematic study of the effects of poling time and applied voltage o
n second-harmonic (SH) generation in thermally poled silica glass reve
als that the SH signal is proportional to the square of the applied vo
ltage and that the speed of the poling process increases with the appl
ied voltage. Prior treatment of the samples is found to affect the pol
ing process, and the optimum poling conditions are observed to depend
on the poling atmosphere. The mechanism of thermal poling is discussed
in the light of these new results. (C) 1996 Optical Society of Americ
a